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Rhenium & Alloys

History of Rhenium and Alloys Material in 1650 degree C FurnaceRhenium was an unknown element when the periodic table was introduced in 1870. The properties predicted for an element of atomic #75 turned out to be in general agreement of those of rhenium when it was discovered in 1925. W. Noddack and O. Berg were the first to locate it in platinum ores such as columbite and tungstate. J.G.F. Druce discovered it independently in manganese sulphate. The ores from which rhenium was first extracted commercially came from the region of the river Rhine (Latin: Rhenus) hence the name rhenium was born.
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Fabrication and Applications of Rhenium and Rhenium Alloys

Arc melting of rhenium in an inert atmosphere or vacuum is possible but the metal produced tends to have coarse grain size and may have segregation of rhenium oxides at the grain boundaries. These issues are a problem for further fabrication and powder metallurgy is the preferred answer to the problem. Rhenium powder is consolidated at pressure to a density of approximately 60% of the theoretical density of solid rhenium.

The pressed compacts are then presintered in a hydrogen atmosphere to facilitate handling before final sintering. Rhenium alloys are produced by the same production methods as used for rhenium. Proper choice of powder sizes, careful blending and adequate sintering times and temperatures produce bars of hi yield and small grain size with the same homogeneity attainable by electron beam or arc melting. Subsequent fabrication is performed by swaging, rolling, forging and drawing with intermediate annealing. Some of these operations may have to be conducted at elevated temperatures. The optimum sequence of these operations varies for rhenium ad it alloys and depends on the final end form.

Applications

Additive to tungsten and molybdenum-based alloys to increase ductility at higher temperatures

Filaments for mass spectrographs and ion gauges

Rhenium-molybdenum alloys become super-conducting at 10K

Electrical contact material, as it has good wear resistance and withstands arc corrosion

Thermocouples made of Re-W are used for measuring temperatures up to 2200° C

Rhenium wire is used in flash lamps for photography

Rhenium can also be used in medical applications. While it is non-radioactive by nature it can be made radioactive by neutron bombardment. Radioactive rhenium is used in prevention and treatment of restenosis, which develops following balloon angioplasty. Rhenium can also be highly effective in the treatment of liver tumors.

H. Cross Company can supply your rhenium needs in two grades, the standard 99.98% minimum purity and for spectrographic filaments or applications requiring the highest purity a 99.999% zone refined rhenium. We can supply wire, rod, sheet, foil, strip or ribbon in the standard grade product and foil, ribbon or strip in the zone refined product. Thickness down to .0004, diameters down to .002and widths up to 3are available with tolerances to meet the most demanding applications.



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